2-乙基己基膦酸单(2-乙基已基)酯萃取钴的动力学  

KINETICS OF COBALT EXTRACTION WITH MONO-（2-ETHYLHEXYL）2-ETHYLHEXYL PHOSPHONIC ACID FROM NITRATE SOLUTION

作　　者：郑佐西[1] 顾忠茂[1] 汪德熙[1] 

机构地区：[1]中国原子能科学研究院,北京102413

出　　处：《化工学报》1996年第1期115-119,共5页CIESC Journal

摘　　要：The kinetcs of extraction of cobalt with HEHEHP-kerosene solution from aqueous nitrate solution has been studied using the Lewis Cell.The effects of stirring rate and interfacial area were investigated.In the kinetic region,the influences of concentration of cobalt,hydrogen ion and HEHEHP were mainly studied.The effects of the sulphate,chloride,nitrate and acetate ions in aqueous phase on extraction rate were also discussed. The experimental results indicate that the extraction process may be governed by the mixed mechanism of diffusion and chemical reaction.In the kinetion,region，the extraction Process might be controlled by the following interfacial reactions The apparent rate constant was calculated to be about 3.63×10-13mol·cm-2·s-1.The sulphate,nitrate and chloride ions decrease the extraction rate in the order of SO42-＞NO-3＞CI-.On the other hand,the acetate ion could greatly increase the extraction rate.The extraction rate with 0.025mol·L-1 acetate ion in aqueous phase is about four times of that without acetate ion.The kinetcs of extraction of cobalt with HEHEHP-kerosene solution from aqueous nitrate solution has been studied using the Lewis Cell.The effects of stirring rate and interfacial area were investigated.In the kinetic region,the influences of concentration of cobalt,hydrogen ion and HEHEHP were mainly studied.The effects of the sulphate,chloride,nitrate and acetate ions in aqueous phase on extraction rate were also discussed. The experimental results indicate that the extraction process may be governed by the mixed mechanism of diffusion and chemical reaction.In the kinetion,region，the extraction Process might be controlled by the following interfacial reactions The apparent rate constant was calculated to be about 3.63×10^(-13)mol·cm^(-2)·s^(-1).The sulphate,nitrate and chloride ions decrease the extraction rate in the order of SO_4^(2-)＞NO^(-3)＞CI^-.On the other hand,the acetate ion could greatly increase the extraction rate.The extraction rate with 0.025mol·L^(-1) acetate ion in aqueous phase is about four times of that without acetate ion.

关 键 词：动力学 萃取 钴 乙基 已基 膦 酸单酯 分离 

分 类 号：O652.6[理学—分析化学]