Synthesis and ion-binding studies of platinum(Ⅱ)phenanthroline complexes containing crown ether moiety  

Synthesis and ion-binding studies of platinum(II) phenanthroline complexes containing crown ether moiety

作　　者：HAN Xue WU Lizhu ZHANG Liping TUNG Chenho 

机构地区：[1]Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, China

出　　处：《Chinese Science Bulletin》2006年第8期1005-1009,共5页

基　　金：supported by the National Natural Science Foundation of China(Grant Nos.20125207,20333080,20332040 and 50473048);Chinese Academy of Sciences and the Ministry of Science and Technology of China(Grant Nos.2003CB716802 and 2004CB719903).

摘　　要：Two new benzo-[15]-crown-5 attached phenanthroline platinum(II) complexes with the gen- eral formula Pt(phen)X2, where X = Cl (1), C≡CC6H5 (2) have been synthesized, and their absorption and luminescence response towards metal ions have been studied.Two new benzo-[15]-crown-5 attached phenanthroline platinum（Ⅱ） complexes with the general formula Pt（phen）X2, where X = Cl （1）, C=CC6H5 （2） have been synthesized, and their absorption and luminescence response towards metal ions have been studied.

关 键 词：邻二氮杂菲 铂 MLCT 合成 离子束缚 乙醚 

分 类 号：O614.826[理学—无机化学]