K改性β-Mo_2C催化剂CO加氢合成低碳混合醇的研究  

Mixed alcohols synthesis from CO hydrogenation over potassium-promoted β-Mo_2C catalysts

作　　者：向明林[1] 李德宝[1] 肖海成[1] 齐会杰[1] 李文怀[1] 孙予罕[1] 钟炳[1] 

机构地区：[1]中国科学院山西煤炭化学研究所煤转化国家重点实验室

出　　处：《燃料化学学报》2006年第2期200-204,共5页Journal of Fuel Chemistry and Technology

摘　　要：制备系列K改性的β-Mo2C催化剂并对其CO加氢合成低碳混合醇性能进行了考察。结果表明，K改性使β-Mo2C催化剂的c0加氢选择性发生显著变化。β-Mo2C催化剂CO加氢的产物主要为C1～C4烷烃，经K改性后β-Mo2C催化剂上产物主要为C1～C5低碳醇，其中高级醇（C2，OH）选择性可达到33．78％。通过对碱金属质量分数的考察发现，当K／Mo（原子比）为0．2时，总醇选择性达到最大值，低碳醇的时空收率达到0．12g／（mL·h^-1）。β-Mo2C催化剂上醇烃产物均符合线性Anderson-Schultz-Flory（A-S-F）分布曲线，而K改性β-Mo2C催化剂上醇产物为独特的甲醇负偏离A-S-F分布。可见，K助剂的加入有效促进了低碳醇的形成，尤其是促进了C1OH到C2OH的链增长步骤。The modification effects of KECO3 on β-Mo2C catalysts for mixed alcohols synthesis from CO hydrogenation were studied. Un -promptedfl-MOEC produced mainly hydrocarbons of C1-C4 under the reaction conditions of 573 K, 8.0 MPa, H2/CO = 1.0, GHSV = 2 000 h^-1. Addition of KECO3 to β-Mo2C resulted in remarkable selectivity shift from hydrocarbons to alcohols. Moreover, the promoter of potassium enhanced the ability of chain propagation of β-Mo2C with the higher selectivity of C2＋ alcohols. The investigations of the loadings of K2CO3 in β-Mo2C revealed that the maximum of alcohol yield obtained at K/Mo （molar ratio） =0.2. On K/β-Mo2C catalysts, the distribution of hydrocarbons obeyed the traditional linear Anderson - Schultz - Flory equation, while the distribution of alcohols gave a unique linear Anderson-Schultz-Flory with remarkable deviation of methanol. Thus, potassium promoter exerted a prominent function on the whole chain propagation to produce alcohols especially for the stage of methanol to ethanol.

关 键 词：β-Mo2C催化剂 K改性 CO加氢 低碳混合醇 

分 类 号：O643[理学—物理化学]