原位缩聚合成含聚芳酰胺/酯的微相复合材料 Ⅳ.全芳香聚酰胺与聚砜的微相复合材料制备  

Aromatic polyamide (or polyester)-containing microcomposites by in-situ polycondensation Part Ⅳ. Synthesis of poly(p-phenylene terephthalamide)/polysulfone microcomposites

作　　者：黄双武 吴美琰[2] 张树范[2] 

机构地区：[1]美光半导体亚洲有限公司,新加坡339942 [2]中国科学院化学所,北京100080

出　　处：《合成技术及应用》2006年第1期15-19,共5页Synthetic Technology & Application

摘　　要：以原位缩聚方法合成了PPTA/PSF的微相复合材料。FTIR、DSC等分析结果表明,PPTA/PSF微相复合材料较PPTA/PBT-PTMG分子链间存在着更强的相互作用,PPTA对基体聚合物的力学性能有较大的提高。初步结果表明,加入第三单体双酚A在一定程度上提高了复合材料的抗张强度和断裂伸长率,但是模量有所下降。PPTA/PSF microcomposites are prepared by in-situ polycondensation. The strong molecular interactions in this system are confirmed using FTIR、 DSC and other techniques. Compared with previous PPTA/PBT-PTMG system, this system has much stronger interaction between rigid and flexible polymers. Therefore, at the same content of PPTA, the mechanical properties of PPTA/PSF microcomposites increased much more than those of PPTA/PBT-PTMG microcomposites. Preliminary results show that the addition of the third monomer biphenol A improved the tensile strength and uhimate elongation, but decreased the modulus of the microcomposites.

关 键 词：微相复合材料 原位缩聚 聚对苯二甲酰对苯二胺 聚砜 分子间相互作用 

分 类 号：TQ316.33[化学工程—高聚物工业]