聚丙烯/POE共混组成对材料断裂行为的影响  

FRACTURE BEHAVIOR OF POLYPROPYLENE/POE BLENDS WITH DIFFERENT MIXED RATIOS

作　　者：谢邦互[1] 沈岳新[1] 李忠明[1] 杨伟[1] 冯建民[1] 杨鸣波[1] 

机构地区：[1]四川大学高分子科学与工程学院高分子材料工程国家重点实验室,成都610065

出　　处：《高分子学报》2006年第2期335-339,共5页Acta Polymerica Sinica

基　　金：国家自然科学基金(基金号50373027);中石化基础研究项目(项目号X504004)资助

摘　　要：采用基本断裂功(EWF)方法对聚丙烯(PP)/聚烯烃弹性体(POE)共混物的注射双边缺口拉伸试样的断裂行为进行了研究,比较了不同POE含量对共混物各断裂参数的影响.结果表明,PP和用量为5phr POE的共混物都可完全满足EWF方法的要求,共混物的断裂韧性-比基本断裂功we,较PP有显著提高;POE用量为10phr以上的共混物则出现明显的成颈现象而限制了EWF方法的应用;PP和各种POE用量的共混物都得到了其屈服所需要的比基本断裂功we,y和比塑性功β′wp,y.The influence of polyolefin elastomer （POE） content of polypropylene （PP）/POE blends on fracture behavior has been studied using the essential work of fracture （EWF） method. Each material was injected for preparing double edge-notched tensile （DENT） specimens of about 1.3 mm thickness. It was established that the essential work of fracture approach worked well for the PP and PP/POE （100/5） blend .The specific essential work of fracture, we, increased remarkably with adding POE. Some limitations of the EWF method was found with PP/POE （100/10 and 100/15） blends, which showed the necking phenomenon with DENT specimens studied. The specific essential work and plastic work of fracture required for yielding, W o.y and β＇Wp,y, of each material were obtained. It was found that the We,y values of the PP/POE blends all increased remarkably, over two times larger than that of pure PP, and the β＇wp,y values increased gradually with increasing content of POE for the PP/POE blends.

关 键 词：聚丙烯 聚烯烃弹性体 断裂行为 基本断裂功 塑性变形 

分 类 号：TQ317[化学工程—高聚物工业]