停流分光光度法研究铁卟啉与肼反应动力学  

STUDY ON KINETICSOF REACTION BETWEEN IRON PORPHYRIN AND HYDRAZINE HYDRATE BY STOPPED-FLOW METHOD

作　　者：钟新华[1] 黄杰生[1] 周永洽[1] 林华宽[1] 卜显和[1] 申泮文[1] 

机构地区：[1]南开大学化学系,天津300071

出　　处：《无机化学学报》1996年第2期126-129,共4页Chinese Journal of Inorganic Chemistry

基　　金：天津市 2 1世纪青年基金资助课题

摘　　要：用停流分光光度法研究了氯代四苯基卟啉铁 ( ) [Fe T(p- X) PPCl,X=H,CH3 ]与肼在二氯甲烷溶液中的反应动力学 ,求得了不同温度下反应的速率常数及活化参数 ,初步探讨了反应机理。The kinetics of reaction between chloroiron tetraphenylprophyrin Fe T(p- X) PPCl(X= H,CH3 ) and hydrazine hydrate in dichloromethane solution was investigated.The rate constant of the reaction at various temperature and active parameters were obtained. The mechanism of the reaction was explored.

关 键 词：铁卟啉 肼 动力学 停流分光光度法 

分 类 号：O614.811[理学—无机化学] O657.32[理学—化学]