丝光沸石前驱体组装MCM-41介孔分子筛  被引量:6

Mesoporous Molecular Sieves MCM-41 Assembled From Performed Zeolite Mordenite Precursors

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作  者:潘瑞丽[1] 李玉平[1] 张伟[1] 闫子春[1] 窦涛[1,2] 

机构地区:[1]太原理工大学精细化工研究所 [2]石油大学化工学院CNPC催化重点实验室,北京102249

出  处:《分子催化》2006年第2期173-175,共3页Journal of Molecular Catalysis(China)

基  金:国家自然科学基金(批准号:20476060);国家重大基础研究项目(973)2004CB217806.

摘  要:Mesoporous Molecular Sieves were successfully synthesized by using the performed zeolite mordenite precursors as silica source. The synthesized samples were characterized by XRD, FT-IR , N_ 2 adsorption and desorption and hydrothermal treatment methods. The results demonstrated that the synthesized samples were similar to the conventional structure MCM-41 in the ordered hexagonal structure and were superior to conventional MCM-41 with respect to their higher hydrothermal stability. It is suggested that secondary structure units of mordenite zeolite were introduced into the mesoporous wall that makes the contribution of the highly hydrothermal stability of Mesoporous Molecular Sieves.Mesoporous Molecular Sieves were successfully synthesized by using the performed zeolite mordenite precursors as silica source. The synthesized samples were characterized by XRD, FT-IR , N2 adsorption and desorption and hydrothermal treatment methods. The results demonstrated that the synthesized samples were similar to the conventional structure MCM-41 in the ordered hexagonal structure and were superior to conventional MCM-41 with respect to their higher hydrothermal stability. It is suggested that secondary structure units of mordenite zeolite were introduced into the mesoporous wall that makes the contribution of the highly hydrothermal stability of Mesoporous Molecular Sieves.

关 键 词:丝光沸石 次级结构单元 介孔分子筛 

分 类 号:O643.32[理学—物理化学]

 

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