高碳烯烃氢甲酰化研究进展  

Review on Hydroformylation of Higher Olefins

作　　者：马占华[1] 刘雪暖[1] 杨国华[1] 

机构地区：[1]中国石油大学(华东)化学化工学院,山东东营257061

出　　处：《化学工业与工程》2006年第3期265-270,共6页Chemical Industry and Engineering

摘　　要：水/有机两相催化体系被成功应用于低碳烯烃氢甲酰化反应。对于水溶性差的高碳烯烃,其氢甲酰化反应速度远远低于低碳烯烃。本文论述了近年来铑催化高碳烯烃氢甲酰化反应的研究和开发进展,其新型配体和新催化体系的研究开发一直是该领域的研究热点。主要涉及两相反应体系中的水溶性膦配体以及均相催化剂固相化、氟两相催化、非离子液体催化体系和超临界CO2中的氢甲酰化反应等几种新型反应体系。Water-soluble rhodium-phosphine complexes have been successfully applied in lower olefin hydroformylation. For higher olefin that has poor solubility in water, the hydroformylation reaction rate is much less than short-chain alkenes. This review covers the recent advances in Rh-catalysed hydroformylation of higher olefin, most of investigations in this field focus on the synthesis of new effective phosphine ligands and new catalysis systems. In particular, the developments of new-style reaction system, such as water-soluble phosphine in two-phase catalysis system, the supported catalysts,fluorous biphase system, non-aqueous ionic liquids catalysis and hydroformylation in supercritical carbon dioxide were mainly introduced in this paper.

关 键 词：氢甲酰化 水溶性膦配体 担载水相催化剂 多相反应体系 

分 类 号：O623.121[理学—有机化学] TQ224.129[理学—化学]