氯丙基取代的杯芳烃衍生物的合成  

Synthesis of Three-methyl-chlorine-substituted Calixarenes Derivatives

作　　者：朱建国[1] 朱晓红[2] 武家荣[1] 

机构地区：[1]连云港师范高等专科学校化学系,江苏连云港222006 [2]海州高级中学化学教研室,江苏连云港222023

出　　处：《河南科技大学学报（自然科学版）》2006年第1期92-95,共4页Journal of Henan University of Science And Technology:Natural Science

基　　金：江苏省教育厅科研基金项目(2002-J-251)

摘　　要：以对叔丁基杯[n]芳烃1a-1c(n=4,6,8)和间苯二酚杯芳烃1d-1e(R=C6H5,p-HOC6H4)为原料,在碳酸钾存在下以丙酮为溶剂与1-溴-3-氯丙烷反应,得到下缘为氯丙基取代的杯芳烃衍生物2a-2e。进一步以2b-2d为原料,在碳酸钾存在下以丙酮为溶剂与咔唑反应,得到丙基桥连的杯芳烃咔唑衍生物3a-3c。通过红外光谱,核磁共振氢谱等确定了上述产物的结构。Tert-butylcalixarenes 1a-1c(n=4,6,8) or resorcinarenes 1d-1e(R=C_6H_5,p-HOC_6H_4) were alkylated by 1-bromine-3-chloropropane in refluxing acetone with anhydrous K_2CO_3 as solid base.To get and make cup aromatic hydrocarbon derivative 2a-2e that reason replaced for third base of chlorine.React with 2b-2d so as to acetone for the solvent and carbazole under potassium have in carbonic acid to step forward,get cup aromatic hydrocarbon carbazole derivative 3a-3c connected with in third base bridge.The structures of all new products were characterized by IR and 1HNMR spectroscopy.

关 键 词：杯芳烃 氯丙基 烃基化反应 取代 

分 类 号：O625.1[理学—有机化学]