无配体Pd/LDH-F催化剂在Heck和Suzuki反应中的应用  

Application of Ligand-Free Pd/LDH-F Catalyst in Heck and Suzuki Coupling Reactions

作　　者：周浩[1] 卓广澜[2] 姜玄珍[1] 张波[3] 葛忠华[3] 

机构地区：[1]浙江大学化学系,浙江杭州310027 [2]浙江理工大学应用化学系,浙江杭州310012 [3]浙江工业大学化工学院,浙江杭州310014

出　　处：《催化学报》2006年第4期335-338,共4页

基　　金：国家自然科学基金(20476092);绿色化学国家重点实验室资助项目

摘　　要：以氟离子插层的水滑石LDH-F为载体,用逐滴浸渍法制备了新型Pd/LDH-F催化剂,并用其催化溴代芳烃的Heck和Suzuki偶联反应.用X射线衍射表征了催化剂的晶相,以等离子体发射光谱测定了溶剂中钯的流失量.结果表明,对于Heck反应,在无配体存在和低钯用量(Pd/溴代芳烃摩尔比为0.001)的情况下,Pd/LDH-F的催化性能优于其它载体负载的Pd催化剂,显示出很高的催化活性和选择性.在140℃和12 h的条件下,Pd/LDH-F催化溴苯与苯乙烯Heck反应产物的收率可达86%,反应后催化剂经过分离,可循环使用四次其催化活性基本不变.在DMF/水摩尔比为0.5的混合溶剂中,在室温和3h的条件下,Pd/LDH-F(Pd/溴代芳烃摩尔比为0.005)催化溴苯与苯基硼酸盐的Suzuki反应中,目标产物收率为99%.The palladium catalyst supported on fluoride pillared layered double hydroxide （LDH-F） was prepared by the incipient wetness method, and it was used to catalyze the Heck and Suzuki coupling reactions of aryl bromides, The structure of the Pd/LDH-F catalyst and the leaching of Pd in the solution were characterized by X-ray diffraction and inductively coupled plasma. With a small palladium dosage （Pd/aryl bromide molar ratio of 0.001） and no ligand, Pd/LDH-F exhibits higher catalytic activity and selectivity than the catalysts supported on other carriers for the Heck reaction of aryl bromides with styrene. The Pd/LDH-F catalyst can be easily separated from the reaction mixture and reused four times without loss in activity. Under the conditions of Pd/aryl bromide molar ratio of 0.005, room temperature and 3 h, the Pd/LDH-F catalyst can catalyze the Suzuki reaction of bromobenzene with a product yield of 99 %.

关 键 词：钯 氟 水滑石 负载型催化剂 溴代芳烃 HECK反应 SUZUKI反应 

分 类 号：O643.32[理学—物理化学]