硫杂杯[4]芳烃酰胺基硫脲衍生物的合成  

Synthesis of Thiacalix[4] arene Derivatives Containing Amide and Thiourea Units

作　　者：黄翠玉[1] 杨发福[1] 赵夏[1] 郭红玉[1] 林建荣[1] 

机构地区：[1]福建师范大学化学与材料学院,福建福州350007

出　　处：《合成化学》2006年第3期264-265,268,共3页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(20402002);福建省自然科学重点基金资助项目(E0220002)

摘　　要：硫杂杯[4]芳烃四乙酸乙酯衍生物与水合肼反应生成硫杂杯[4]芳烃四酰肼衍生物(3),3与异硫氰酸苯酯反应得到新型硫杂杯[4]芳烃酰胺基硫脲衍生物,总产率61%。Thiacalix[ 4 ] arene hydrazides derivative（3） was obtained by the reaction of thiacalix[ 4 ] arene tetra-ethylacetates with hydrazine hydrate. Treatment of 3 with phenyl isothiocyanate, a novel thiacalix[ 4 ] arene derivative containing amide and thiourea units was obtained. The total yield was as high as 61%.

关 键 词：硫杂杯[4]芳烃 酰胺 硫脲 合成 

分 类 号：O623[理学—有机化学]