Thermal effects on structure and photoluminescence properties of diamond-like carbon films prepared by pulsed laser deposition  

作　　者：CHEN Da LI Qing-shan WANG Jing-jing ZHENG Xue-gang 

机构地区：[1]College of Physics and Engineering, Qufu Normal University, Qufu 273165, China

出　　处：《Optoelectronics Letters》2006年第3期182-185,共4页光电子快报（英文版）

摘　　要：Un-hydrogenated Diamond-like Carbon （DLC） films were prepared by pulsed laser deposition technique at different substrate temperature. The Raman spectra, the absorption and the photoluminescence spectra were measured. The dependence of structure and phetoluminescence properties on deposition temperature were studied in detail. The experimental results indicate that the sp^2 sites form small clus ters that consist of both olefinic chains and aromatic ring groups within the sp^3 matrix. With raising deposition temperature,the optical band gaps increase from 1.87 to 2.85 eV. The main band of photoluminescence centered at around 700nm shifts to short wavelength, and the intensity of this band increases. The photoluminescence can be attributed to carrier localization within an increasing sp^2 clusters. It was clarified that the DLC films are ordered with increasing deposition temperature.

关 键 词：碳薄膜 光致发光 金刚石 脉冲激光沉积作用 光谱 

分 类 号：O484.5[理学—固体物理]