萘衍生物的聚合膜结构及膜的pH响应  

The Structure of Polymer Films of Naphthalene Derivatives and pH Response Characteristics of the Polymer Films

作　　者：黄杉生[1] 李苾芬[1] 林辉概[1] 俞汝勤[1] 

机构地区：[1]湖南大学化学化工系

出　　处：《湖南大学学报（自然科学版）》1996年第2期36-40,共5页Journal of Hunan University:Natural Sciences

摘　　要：以电化学方法得到一系列的萘衍生物聚合膜．通过Ｘ－光电子能谱，反射红外光谱方法研究了聚（１－萘胺）的聚合形式．采用量子化学计算得到本文所研究的萘衍生物的电荷密度、分子总能量等电子结构参数．发现这些聚合膜的ｐＨ响应与其电子结构参数有一定的关系．The polymer films of naphthalene, including naphthylamine, naphthalenol and aminonaphthalenol, were obtained by electrochemical polymerization method. The polymerization form of 1-naphthylamine was studied by the infrared spectroscopy, X-photoelectron spectrometry and verified by quantum chemical calculation.It has been found that the pH response characteristics of the polymer films related to the molecular parameters.

关 键 词：萘 衍生物 聚合膜 PH响应 

分 类 号：O657.1[理学—分析化学]