新型含葡萄糖基手性Salen配体及其Mn^(3+)、Fe^(3+)、Co^(2+)、Cu^(2+)配合物的合成与表征  

Synthesis and Characterization of a Novel Chiral Salen Ligand with a Glucose Moiety and Its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ) and Cu(Ⅱ) Complexes

作　　者：赵姗姗[1] 赵继全[1] 赵东敏[1] 

机构地区：[1]河北工业大学化工学院,天津300130

出　　处：《无机化学学报》2006年第6期1133-1136,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.20376017)。

摘　　要：A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-5-(3-tert-butyl-2-hydroxy benzaldehyde) -α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2：5,6-di- O-isopropylidene-3-O-methylene-[5-（3-tert-butyl-2-hydroxy benzaldehyde）]-α-D-glucofuranose with （1R,2R）-1,2- diaminocyclohexane. Several chiral complexes of Mn^3＋、Fe^3＋、Co^2＋ and Cu^2＋ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.

关 键 词：葡萄糖衍生物 手性金属配合物 SALEN配体 SCHIFF碱 环己二胺 

分 类 号：O614.81[理学—无机化学] O614.121[理学—化学]