手性相转移催化剂及其在不对称催化反应中的应用  

Progress of the Chiral Phase Transfer Catalysts and the Applications in Asymmetric Catalytical Reaction

作　　者：曾莎莎[1] 唐瑞仁[1] Artem Melman 黄可龙[1] 

机构地区：[1]中南大学化学化工学院 [2]Department of Organic Chemistry,Hebrew University of Jerusalem,Jerusalem 91904,Israel

出　　处：《化学进展》2006年第6期743-751,共9页Progress in Chemistry

摘　　要：综述了手性季铵盐、手性冠醚以及其它新型手性相转移催化剂的制备及其在各种不对称相转移催化反应如烷基化反应、Michael加成反应、Aldol反应、Mannich反应、氧化反应及还原反应中应用的最新进展。Chiral phase transfer catalysts such as chiral quartemary ammonium salts, chiral crown ethers and their recent advances in the applications in asymmetric catalytic reactions including the alkylation, Michael addition, aldol reaction, Mannich reaction, oxidation and reduction are reviewed in this paper.

关 键 词：手性相转移催化剂 不对称催化反应 手性季铵盐 手性冠醚 相转移催化反应 

分 类 号：O621.25[理学—有机化学] O643.3[理学—化学]