新型偶氮苯的质谱特征与非线性光学性质  

Synthesis, Characteristics of Mass Spectra and Nonlinear

作　　者：颜星中[1] 何宜[1] 杨佩青[1] 姚钟平[1] 蔡志岗[1] 

机构地区：[1]中山大学超快速激光光谱学国家重点实验室 高分子研究所 测试中心

出　　处：《中山大学学报（自然科学版）》1996年第4期7-12,共6页Acta Scientiarum Naturalium Universitatis Sunyatseni

基　　金：广东省自然科学基金;广东省博士后基金资助项目

摘　　要：合成了偶氮苯染料－４－硝基４′－二（Ｎ，Ｎ′－羟乙基）氨基偶氮苯及其３个衍生物．染料分子的质谱行为与分子内电荷转移态有关，存在优势的Ｍ＋１碎片峰．nitro 4′ (N,N′dihydroxyethyl) amino azobenzene and its three derivatives (R HANB)have been synthesized. In their “push pull” electron system, the electron transition between ground state and the intramolecular charge transfer state was observed by UV Vis spectra in polar solvents. Dealing with solvatochromic method, the composite values of the second order optical polarizabilities ( β CT )and the ground state permanent dipole moments( μ g)were obtained. The M+1 peaks of FAB Mass spectra for R HANB seem to berelated with the processes of thermal hydrogen transfer in their intra molecular charge transfer structures.

关 键 词：偶氮苯染料 非线性光学效应 热氢转移 质谱特征 

分 类 号：TQ613.1[化学工程—精细化工]