蓝色有机发光材料LiBq_4的合成及其发光特性  

Synthesis and Luminescence Properties of Blue Organic Light-emitting Material LiBq_4

作　　者：郑代顺[1] 钱可元[1] 张福甲[2] 

机构地区：[1]清华大学深圳研究生院,广东深圳518055 [2]兰州大学物理科学与技术学院,甘肃兰州730000

出　　处：《发光学报》2006年第3期367-372,共6页Chinese Journal of Luminescence

基　　金：国家自然科学基金资助项目(60276026)

摘　　要：蓝色有机发光材料的开发对于实现有机发光二极管(OLED)的全彩色化具有十分重要的意义。报道了蓝色有机发光材料8-羟基喹啉硼化锂(L iBq4)的合成及提纯,研究了L iBq4的光致发光特性,并用L iBq4作为发光材料制备了蓝色有机发光器件,研究了电子传输层A lq3的厚度及空穴缓冲层CuPc对器件电流-电压和亮度-电压特性的影响。结果表明,L iBq4的光致发光峰值波长为452 nm,器件ITO/PVK∶TPD/L iBq4/A lq3/A l的电致发光光谱峰值波长位于475 nm处,在25 V工作电压下其最高亮度约为430 cd/m2。但CuPc的加入加剧了器件中载流子的不平衡注入,导致器件性能恶化。通过调整A lq3的厚度,同时在A lq3和A l阴极之间加入L iF薄膜以提高电子注入效率,获得了较为理想的实验结果。Synthesis of blue organic light-emitting materials is very important for practical applications of organic light-emitting diodes （OLEDs）. Organometallic complex lithium tetra-（8-hydroxy-quinolinato） boron （LiBq4） was synthesized, purified and used as light-emitting material. Blue ITO/PVK： TPD/LiBq4/Alq3/Al OLED was fabricated adopting spin and vacuum deposition, and the electroluminescence spectrum was measured at different operation voltage. At the same time, the influence of thickness of Alq3, CuPc and LiF on the luminescence properties of blue OLEDs was studied. Results indicated that, the peak wavelength of fluorescence spectrum for LiBq4 is about 452 nm under excitation of 350 nm. The peak wavelength of electrol spectrum for blue OLED ITO/PVK： TPD/LiBq4/Alq3/Al device locates at 475nm, and one weak shoulder peak appears at about 500nm, this is resulted from excitation of Alq3. The luminance of this blue OLED can reach 430 cd/m^2 at 25 V operate voltage. As electron transfer material, the thickness of Alq3 film has distinct influence on the electroluminescence spectra and luminance of blue OLEDs. Through adjusting the thickness of Alq3 layer, the recombination region of holes and electrons can be restricted in LiBq4, and the shoulder peak will weaken and disappear. The optimal thickness of Alq3 film is about 10 nm. Although the addition of CuPc between ITO and PVK： TPD could enhance the injection ability of holes, simultaneously induces the imbalance injection of charge carriers, and deteriorates the properties of blue OLED. The addition of LiF thin film between Alq3 and Al cathode could enhance the injection ability of electrons, and makes the injection of electrons reach equilibrium with holes. So the recombination probability of holes and electrons was improved and the luminance of blue OLED was improved evidently. These results were explained with the schematic energy level structure of the blue OLEDs.

关 键 词：LiBq4 蓝色 OLED 合成 发光特性 

分 类 号：TN873.3[电子电信—信息与通信工程] TN383.1