疏水缔合水溶性聚合物合成新方法  

The New Methods of Synthesis of HydrophobicallyAssociating Water-soluble Polymers

作　　者：齐从丽[1] 钟敬敏[1] 焦瑞琴[1] 

机构地区：[1]中国石化西南分公司工程技术研究院,四川德阳618000

出　　处：《中外能源》2006年第3期45-49,共5页Sino-Global Energy

摘　　要：综述了疏水缔合型水溶性聚合物及其合成方法,包括共聚合法(非均相、均相、胶束、反相微乳液、无皂乳液以及阴离子聚合)和大分子反应法。同时,介绍了合成过程中提高油溶性单体和水溶性单体混溶性的方法,简述了合成方法对聚合物结构的影响。This paper reviews various methods of synthesis of hydrophobically associating water-soluble polymers,including copolymerization of acrylamide with hydrophobic monomers （heterogeneous process,homogeneous process,micellar copolymerization,inverse microemulsion process,emulsion process without emulsifying agents and anionic copolymerization）and macromolecular reactions.Meanwhile,it introduces the methods which are to increase the miscibility of oil-soluble and water-soluble monomers during synthetic process.And it illuminates the effection of the methods of synthesis on the structures of polymers.

关 键 词：疏水缔合聚合物 合成 非均相 均相 胶束 反相微乳液 无皂乳液 阴离子聚合 油溶性单体 水溶性单体 

分 类 号：TQ316.3[化学工程—高聚物工业]