3,5-二硝基水杨酸表面修饰纳米TiO_2吸附对硝基苯酚  

Adsorption of p-Nitrophenol by Nanosized Titanium Dioxide Surface Modified with 3,5-dinitrosalicylic Acid

作　　者：郑凤英[1] 钱沙华[1] 李顺兴[2] 陈智煜[2] 

机构地区：[1]武汉大学环境科学系,武汉430072 [2]漳州师范学院化学系,漳州363000

出　　处：《环境科学》2006年第6期1140-1143,共4页Environmental Science

基　　金：国家自然科学基金项目(20177017);福建省青年科技人才创新项目(2003J035)

摘　　要：化学吸附法合成3，5-二硝基水杨酸表面修饰的TiO2纳米粒子，TiO2表面修饰后呈浅黄色，Ti02表面羟基与3，5-二硝基水杨酸发生类似于醇和酸间的酯化反应．表层链接有苯环，极性减弱，非极性增强，在水、苯、乙醇中均分散性良好，与芳香族污染物的亲合力增强，有利于吸附去除芳香族污染物．表面修饰的TiO2纳米粒子20mg，在最佳吸附pH值3、吸附时间10min，对100mL对硝基苯酚（3～10mg／L）的吸附率可由改性前的43％增至99．9％．该法吸附效率高，可直接达到一级排放标准，提供了深度处理对硝基苯酚废水的新方法．Nanometer size titanium dioxide modified with 3,5-dinitrosalicylic acid （3,5-DA） was prepared using chemical adsorption method. The influences of surface modification on the adsorption of p-nitrophenol （PNP） and the dispersion in solvent such as water, benzene and ethanol were studied. The 3,5-dinitrosalicylic acid is bonded to the surface hydroxyl from TiO2 nanoparticles, results in the formation of a stable, six-ring complex which color is buff. The 3, 5-DA-modified TiO2 nanoparticles have good dispersive capacity in water, benzene and ethanol. Under the optimum conditions such as pH value 3, adsorption time 10 min, the adsorption ratio of PNP by TiO2 is improved from 43 % to 99.9 % through surface modification. A new method could be used to remove directly 3-10mg/L PNP, and the residual concentrations is below the integrated wastewater discharge standard （GB 8978-1996）.

关 键 词：二氧化钛 表面修饰 纳米粒子 吸附法 对硝基苯酚 芳香族污染物 深度处理 

分 类 号：X703.1[环境科学与工程—环境工程]