二烃基锡双（O，O－二硫代磷酸酯）的合成和波谱研究  

Preparation and Characterization of (O,O dialkyl dithiophosphato)dialkyltin Compounds

作　　者：谢庆兰[1,2] 朱应怀 杨志强[1,2] 

机构地区：[1]南开大学元素有机化学实验室 [2]元素有机化学研究所

出　　处：《合成化学》1996年第3期233-237,共5页Chinese Journal of Synthetic Chemistry

摘　　要：合成了１５个二烃基双（Ｏ，Ｏ－二硫代磷酸酯）化合物。利用ＩＲ、（１Ｈ、１３Ｃ、１１９Ｓｎ）ＮＭＲ表征了化合物的结构。这是一类六配位变形八面体结构的二烃基锡化合物。对化合物的质谱裂解机制进行了讨论。Fifteen bis(O,O dialkyl dithiophosphato)dialkyltin were prepared and their structures were characterized through IR, ( 1H, 13 C, 119 Sn) NMR. The compound has a tin atom in a distorted six coordination octahedron and two anisobidentated dithiophosphate ligands. The breakdown pattern of MS were also discussed.

关 键 词：二烃基锡 二硫代磷酸酯 结构表征 IR NMR 

分 类 号：O627.42[理学—有机化学] O657.33[理学—化学]