茂锆载体催化剂下的乙烯／辛烯共聚及聚合物的^（13）C　NMR研究  

Ethylene/Octene Copolymerization with Supported Zirconocene Catalysts and the￣(13)C NMR Analysis of Copolymers

作　　者：刘胜生[1] 于广谦[1] 黄葆同[1] 

机构地区：[1]中国科学院长春应用化学研究所

出　　处：《应用化学》1996年第4期110-112,共3页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金

摘　　要：茂锆载体催化剂下的乙烯／辛烯共聚及聚合物的^（１３）ＣＮＭＲ研究刘胜生，于广谦，黄葆同（中国科学院长春应用化学研究所长春１３００２２）关键词茂锆载体催化剂，共聚，序列分布，^（１３）ＣＮＭＲ由于茂锆催化剂具有高活性，单一活性中心等特点［１，２］，并且能...Copolymerization of ethylene/octene_1 was investigated by using two types of supported zirconocene catalysts, Zr/MAO/SiO_2 and Zr/MAO/SAA,where SiO_2 and poly(styrene-acrylamide ) (SAA) were used as carriers respectively. The results showed that the catalysts have high copolymerization ability. The triad sequence distribution and mean sequence lengths of monomers in the copolymers have been calculated by 13C NMR data.

关 键 词：催化剂 共聚 NMR 乙烯 辛烯 锆 

分 类 号：O631.12[理学—高分子化学] O631.133[理学—化学]