新的偶氮酚型和酚兰型生色开链冠醚的合成和配位性质  

Synthesis and Complexation Properties of New Azophenol Type and Phenol Blue Type Chromogenic Acyclic Crown Ethers

作　　者：黄枢[1] 孟杰[1] 田宝芝[1] 

机构地区：[1]四川大学化学系,四川成都610064

出　　处：《有机化学》1996年第4期328-334,共7页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金

摘　　要：用酚型开链冠醚1a和1b为原料,在碱溶液中合成了两类生色开链冠醚:一类是与对硝基苯重氮氟硼酸盐反应生成的偶氮酚型(2a和2b):另一类是与N,N-二甲基对苯二胺和K_3[Fe(CN)_6]反应生成的酚兰型(3a和3b)。用紫外-可见光谱法研究了这些生色开链冠醚与碱金属和碱土金属离子的配位性质。发现在THF-H_2O中,2a对LiClO_4和ca(ClO_4)_2,2b对LiClO_4、NaClO_4和Ca(ClO_4)_2,有较显著的选择性变色作用;而3a和3b在CH_3CN中。则对LiClO_4、NaClO_4和各种碱土金属盐,均有不同程度的变色作用,尤其以对Ca^(2+)和Sr^(2+)作用时的△λ_(max)为最大。这些结果表明,2a和2b的配位性质分别与由邻苯二酚衍生的2’a和2’b相似,而3a和3b的配位性质则分别与由邻苯二酚衍生的3’b相似。Two types of new chromogenic acyclic crown ethers were synthesized from the diphe-nols 1a and 1b in alkaline solutions. One is azophenol type compounds 2a and 2b. They were produced by reacting 1a and 1b with p - nitro - benzenediazonium fluoroborate separately. The other one is phenol blue type compounds 3a and 3b. They were obtained from the oxidative condensation of 1a and 1b with N,N - dimethyl - p - phenylenediamine promoted by K3[Fe(CN)6]. Their properties of complexation with alkali and alkaline earth metal ions have been investigated by means of UV - visible spectrometry. It was observed that 2a has apparently selective coloration properties with LiClO4 and Ca(ClO4)2 but 2b was selectively colored with LiClO4, NaClO4 and Ca(ClO)4)2 in THF - H2O (95:5, v/v) . 3a and 3b exhibited some degrees of coloration with Li+ , Na + and several alkaline metal ions, especially with Ca2 + , Sr2+ and Ba2 + in CH3CN. These results show that the complexation properties of 2a and 2b are similar to 2'a and 2'b, and 3a and 3b similar to 3'b.

关 键 词：开链冠醚 配位作用 紫外-可见光谱 偶氮酚 

分 类 号：O623.423[理学—有机化学] O625.65[理学—化学]