侧基上带有C_（60）基团的聚苯乙烯的合成  

Synthesis of Polystyrene with C_(60) in the Side Group

作　　者：汪长春[1] 舒昶[1] 府寿宽[1] 

机构地区：[1]复旦大学高分子科学系

出　　处：《高等学校化学学报》1996年第9期1477-1481,共5页Chemical Journal of Chinese Universities

基　　金：上海市青年教师基金

摘　　要：采用三步连续反应（氯甲基化，叠氮化，环加成反应），成功地将Ｃ_（６０）引入聚苯乙烯的侧基上，并对每一步反应进行了较详细的讨论。Three-step reactions,i.e.,chloromethylation,azidization and cycloaddition,were adopted to introduce C_(60) into the side group of polystyrene successfully, and each step reaction was discussed in detail. The products were proved to be extremely soluble in a variety of organic solvents such as CHCl3, THF, etc.. This solubility behavior is simillar to polystyrene itself and totally unlike C_(60)

关 键 词：氯甲基化 叠氮化 环加成反应 聚苯乙烯 碳60 

分 类 号：O632.13[理学—高分子化学] O635.1[理学—化学]