稀土配合物二硫代氨基甲酸盐类的合成及其性能研究  

Research on the Synthesis and Properties of the Rare Earth N,N-Dibenzyl Dithiocarbamate

作　　者：周红缨 

机构地区：[1]利高曼广州有限公司,广东广州510760

出　　处：《广东化工》2006年第6期19-22,共4页Guangdong Chemical Industry

摘　　要：本文探讨了稀土配合物二硫代氨基甲酸盐类合成条件,并确定配体二苄基二硫代氨基甲酸钠(NaDBTC)反应的最佳条件为:n二苄胺∶nNaOH∶nCS2=1.0∶1.5∶1.8;反应时间在2h。最后,合成了该配体与稀土的配合物。In this paper, the synthesis conditions of N, N-Dibenzyl Dithiocarbamate was discussed. And also the best reaction conditions of NaDBTC was found as ： the mole ratio ofdibenzyl amine, NaOH and CS2 was 1.0 ： 1.5 ＂ 1.8, and the best reaction time was two hours. Finally, its rare earth complexes were prepared.

关 键 词：稀上配合物 合成 

分 类 号：TQ330.385[化学工程—橡胶工业] O614.33[理学—无机化学]