用活性炭负载酸性催化剂合成四氢呋喃  

Synthesis of Tetrahydrofuran Using Acid Catalyst Supported on Granular Active Carbon

作　　者：李继忠[1] 

机构地区：[1]延安大学化学化工学院化学反应工程省级重点实验室,陕西延安716000

出　　处：《化学世界》2006年第6期355-356,370,共3页Chemical World

摘　　要：以活性炭负载对甲苯磺酸作催化剂,对1,4-丁二醇脱水剂制备四氢呋喃的反应进行研究。考察了催化剂用量,反应时间,反应温度等因素对产率的影响。得出了最佳的反应条件:催化剂用量是1,4-丁二醇质量的3.3%,反应时间30 min,产率可达97.36%。Tetrahydrofuran was synthesised by dehydration of 1,4-butanediol using p-toluene sulphonic acid supported on active carbon as catalyst. Various reaction parameters such as catalyst amount, reaction temperature and reaction time were tested. The optimum reaction conditions were ： the amount of catalyst, 3.3 % of the amount of 1,4-butanediol ; and reaction time, 30 rain. The yield of tetrahydrofuran reached 97.36% under the optimum conditions.

关 键 词：1 4-丁二醇 四氢呋喃 活性炭 对甲苯磺酸 

分 类 号：TQ251.1[化学工程—有机化工]