Hydrothermal Synthesis and Structure of [(PbCl_2)(μ-Pyz)_(1/2)]_n (Pyz = Pyrazine)  

作　　者：LIAO Qiu-Xia ZHANG Jian QIN Ye-Yan YAO Yuan-Gen 

机构地区：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on theStructure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

出　　处：《Chinese Journal of Structural Chemistry》2006年第7期789-792,共4页结构化学（英文）

基　　金：This work was supported by the National Natural Science Foundation of China (No. 20173063), the State Key Basic Research and Development Plan of China (001CB108906), and the NSF of Fujian Province (E0020001)

摘　　要：A novel 2-D lead-containing hybrid compound, [（PbCl2）（μ-Pyz）1/2], （Pyz = pyrazine） 1, has been synthesized by the hydrothermal assembly of pyrazine with lead chloride. Elemental analysis and X-ray crystal structure analyses were carded out for the structural determination and characterization of the title compound. Compound 1 crystallizes in orthorhombic, space group lbam, with a = 19.5558（18）, b = 7.1939（6）, c = 7.5449（6） A, V = 1061.44（16） .A^3, C2H2Cl2NPb, Mr= 318.14, Z = 8, Dc= 3.982 g/cm^3, μ = 32.63 mm^-1, F（000） = 1096.0, R = 0.0368 and wR = 0.0901 for 623 observed reflections （I 〉 2σ（I））.A novel 2-D lead-containing hybrid compound, [（PbCl2）（μ-Pyz）1/2], （Pyz = pyrazine） 1, has been synthesized by the hydrothermal assembly of pyrazine with lead chloride. Elemental analysis and X-ray crystal structure analyses were carded out for the structural determination and characterization of the title compound. Compound 1 crystallizes in orthorhombic, space group lbam, with a = 19.5558（18）, b = 7.1939（6）, c = 7.5449（6） A, V = 1061.44（16） .A^3, C2H2Cl2NPb, Mr= 318.14, Z = 8, Dc= 3.982 g/cm^3, μ = 32.63 mm^-1, F（000） = 1096.0, R = 0.0368 and wR = 0.0901 for 623 observed reflections （I 〉 2σ（I））.

关 键 词：crystal structure lead chloride PYRAZINE 

分 类 号：O[理学]