Synthesis and Crystal Structure of 2-Nitrophenyl N,N-Bis(2-chloroethyl)-N'-(4-methylbenzene- sulfonamino)ethyl-phosphorodiamidate  

作　　者：ZHANG Gai-Hong CHEN Ru-Yu HUANG You MIAO Zhi-Wei 

机构地区：[1]Institute and State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China

出　　处：《Chinese Journal of Structural Chemistry》2006年第7期797-800,共4页结构化学（英文）

基　　金：Corresponding author. Chen Ru-Yu, born in 1919, professor, member of the Chinese Academy of Sciences,

摘　　要：The crystal structure of 2-nitrophenyl N,N-bis（2-chloroethyl）-N＇-（4-methylbenzene-sulfonamino）ethyl-phosphorodiamidate （C19H25Cl2N4O6PS） was determined by single-crystal X-ray diffraction analysis. The compound crystallizes in the triclinic system, space group PI^- with a = 9.3664（13）, b = 9.9560（14）, c = 13.1803（18） ,A, α = 87.338（2）, β= 87.632（2）, γ = 79.536（2）°, Dc = 1.484 g/cm^3, Z = 2, λ = 0.71073 A, μ（MoKα） = 0.465, Mr = 539.36, V = 1206.7（3） A^3, F（000） = 560, the final R = 0.0426 and wR = 0.1097 for 3463 observed reflections with I 〉 2σ（I）.The crystal structure of 2-nitrophenyl N,N-bis（2-chloroethyl）-N＇-（4-methylbenzene-sulfonamino）ethyl-phosphorodiamidate （C19H25Cl2N4O6PS） was determined by single-crystal X-ray diffraction analysis. The compound crystallizes in the triclinic system, space group PI^- with a = 9.3664（13）, b = 9.9560（14）, c = 13.1803（18） ,A, α = 87.338（2）, β= 87.632（2）, γ = 79.536（2）°, Dc = 1.484 g/cm^3, Z = 2, λ = 0.71073 A, μ（MoKα） = 0.465, Mr = 539.36, V = 1206.7（3） A^3, F（000） = 560, the final R = 0.0426 and wR = 0.1097 for 3463 observed reflections with I 〉 2σ（I）.

关 键 词：SULFONAMIDE crystal structure phosphorodiamidate 

分 类 号：O[理学]