共价键连卟啉-富勒烯化合物的合成与表征  

Synthesis and Characterization of Covalently Linked Porphyrin-fullerene Compounds

作　　者：凡素华[1] 杨森根[1] 吴振奕[1] 陈昕[1] 詹梦熊[1] 

机构地区：[1]厦门大学化学系,厦门361005

出　　处：《无机化学学报》2006年第7期1299-1302,共4页Chinese Journal of Inorganic Chemistry

基　　金：福建省自然科学基金项目(No.E0410001);厦门大学自选课题基金项目(No.0040-Y07008)

摘　　要：The covalently linked porphyrin-fullerene dyads were synthesized. The ligand 5-[4′-(4″-Phenoxybutoxy)phenyl]-N-(2-methyl)fulleropyrrolidine-10,15,20-tri-(p-methoxyphenyl)porphyrin (H2P-C60) was synthesized by 1,3 dipolar cycloaddition reaction with C60, sarcosine and H2P-CHO. The zinc porphyrin-fullerene was prepared by metalation of H2P-C60 and zinc acetate. The compounds were characterized by meams of IR, UV-Vis, ESI-MS, elemental analysis, and 1H NMR.The covalently linked porphyrin-fullerene dyads were synthesized. The ligand 5-[4＇-（4＂-Phenoxybutoxy） phenyl]-N-（2-methyl）fulleropyrrolidine-10,15,20-tri-（p-methoxyphenyl）porphyrin （H2P-C60） was synthesized by 1,3 dipolar cycloaddition reaction with C60 sarcosine and H2P-CHO. The zinc porphyrin-fullerene was prepared by metalation of H2P-C60 and zinc acetate. The compounds were characterized by meams of IR, UV-Vis, ESI-MS, elemental analysis, and 1H NMR.

关 键 词：卟啉 富勒烯 金属卟啉 

分 类 号：O613.7[理学—无机化学] O614.241[理学—化学]