改进的窗图法优化液相色谱分离二茂铁乙酰甲酰基类衍生物的条件  

OPTIMIZATION OF THE HIGH PERFORMANCE LIQUID CHROMATOGRAPHY SEPARATION OF FERROCENCYLE ACETYL FORMYL DERIVATIVES BY THE DEVELOPED WINDOW DIAGRAM

作　　者：杨学谨[1] 孙成[1] 李松兰[1] 师树简[1] 江景熙 

机构地区：[1]南开大学化学系,内蒙古大学化学系,北京化工学院,江苏药物研究院

出　　处：《南开大学学报（自然科学版）》1996年第3期7-11,共5页Acta Scientiarum Naturalium Universitatis Nankaiensis

基　　金：国家自然科学基金

摘　　要：本文建立了二茂铁乙酰甲酰基类衍生物在高效液相色谱中的保留值与流动相组成的函数关系．对优化液相色谱分离条件的窗图法进行了改进，解决了窗留法在优化液相色谱分离条件中无法程序化的问题，并且根据此优化系统建立了分离该组化合物的最佳流动相体系．In this paper,the functional relationship between the retention value at RP-HPLC and the composition of eluents for eight organometallic compounds has been established.The improved "Window Diagram"method was conducted to make the optimization scheme programed by the use of computer system.In this work,Ferrocencyle acetyl formyl derivatives were successfully separated by the suggested methed.

关 键 词：高效液相色谱 窗图法 二茂铁乙酰甲酰 衍生物 

分 类 号：O627.81[理学—有机化学]