Synthesis and Characterization of a Noncovalently Linked Porphyrin-[1,2-（1 -acridin-10＇-yl-2-aza-2-methylprop-1,3-ylene）- fullerene] Dyad  

作　　者：项云 魏先文 张新明 查庆庆 孙健 尹桂 徐正 

机构地区：[1]College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Normal University, Wuhu, Anhui 241000, China [2]State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, Jiangsu 210093, China

出　　处：《Chinese Journal of Chemistry》2006年第7期862-866,共5页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China （Nos. 20271002, 20490217）, Excellent Young Scholar Foundation （No. 04046065） and the Natural Science Foundation of Anhui Province （No. 00045122）, the Scientific Research Foundation for the Returned 0verseas Chinese Scholars and Excellent Young Teachers Program of the Ministry of Education of China, and the Education Department of Anhui Province （Nos. 2001KJ 115ZD, 2006KJ006TD）.Acknowledgement The authors wish to thank Hu Ji-Ping and Yang Gao- Sheng for their assistance with NMR.

摘　　要：1,2-（1-Acridin-10＇-yl-2-aza-2-methylprop-1,3-ylene）fullerene was synthesized firstly and characterized by UV-Vis, ^1H NMR, ^13C NMR and electrospray ionization mass spectroscopy, which is capable of forming a stable complex with zinc tetraphenylporphyrin via the axial ligation. The steady state fluorescence studies show efficient quenching of the zinc tetraphenylporphyrin emission upon axial coordination of acridine attached to C60.1,2-（1-Acridin-10＇-yl-2-aza-2-methylprop-1,3-ylene）fullerene was synthesized firstly and characterized by UV-Vis, ^1H NMR, ^13C NMR and electrospray ionization mass spectroscopy, which is capable of forming a stable complex with zinc tetraphenylporphyrin via the axial ligation. The steady state fluorescence studies show efficient quenching of the zinc tetraphenylporphyrin emission upon axial coordination of acridine attached to C60.

关 键 词：FULLERENE zinc tetraphenylporphyrin complex self-assembly 

分 类 号：O626[理学—有机化学]