ZSM-5分子筛生成中的模板效应——Ⅲ.季铵盐模板效应的研究  

THE TEMPLATING EFFECT DURING THE FORMATION OF ZSM-5 TYPE MOLECULAR SIEVE Ⅲ. STUDY OF TEMPLATING EFFECT OF QUARTERNARY AMMONIUM SALT

作　　者：宋天佑[1] 刘玺玉 李锡凯[1] 孙习[1] 徐如人[1] 

机构地区：[1]吉林大学化学系,长春130023

出　　处：《Chinese Journal of Catalysis》1990年第4期333-336,共4页催化学报（英文）

摘　　要：ZSM-5分子筛模板效应的研究,已有许多报导。在文献[2]中,我们提出了季铵型化合物具有正电四面体结构,可以用作ZSM-5分子筛的模板剂。但是对烷基链较长的季铵盐,如四己基铵（Hex₄N⁺）、四庚基铵（Hep₄N⁺）及四辛基铵（Oct₄N⁺）的模板效应问题至今未见详细讨论。本工作在合成Hex₄N⁺,Hep₄N⁺及Oct₄N⁺的基础上。On the basis of synthesis of ZSM-5 type zeolites with quartcrnary ammonium salts, XRD, TGA and SEM techniques were used to measure the lattice parameters and to calculate the percentage of the pore volume filled by the templating agent. The templating effect of quartcrnary ammonium salts was discussed. It was found that the templating effect of Hex4N+, Hcp4N + and Ocl4N + was weaker than that of Pr4N+ , and the reasons for the above difference were proposed.

关 键 词：ZSM-5 分子筛 季铵盐 模板效应 

分 类 号：TQ424.25[化学工程]