尼龙6/聚甲亚胺分子复合材料的制备及性能  

Study on Preparation and Properties of Nylon6/Polyazomethine Copolymer

作　　者：王月欣[1] 荆占山[1] 瞿雄伟[1] 贾秀剑[1] 侯伟哲[1] 

机构地区：[1]河北工业大学化工学院高分子科学与工程系,天津300130

出　　处：《高分子材料科学与工程》2006年第4期246-249,共4页Polymer Materials Science & Engineering

基　　金：河北省自然科学基金资助项目(203019)

摘　　要：采用甲苯-2,4-二异氰酸酯对氨端基的聚甲亚胺进行封端,制备大分子活化剂,进而引发ε-己内酰胺进行阴离子聚合制备嵌段共聚物。用FT-IR和W AXD对大分子活化剂的结构和晶型进行了表征。共聚物的力学性能测试表明,当聚甲亚胺的醛/胺摩尔比为4/5时,尼龙6/聚甲亚胺共聚物的冲击强度和拉伸强度都有了明显的提高。The amine-terminated polyazomethine was end-capped by Toluene 2, 4-diisocyanate to synthesize macromolecular activator and then to initiate the anionic caprolactam ringopenning to prepare copolymer. FT-IR was used to characterize the macromolecular activator to prove the existence of the isocyanate; WAXD was also used to characteriz the morphology of the copolymer. Mechanical properties of copolymer indicate that copolymer with 9% PAM content when the molar ratio of aldehyde/amine is 4/5 shows both excellent impact strength and tensile strength.

关 键 词：聚甲亚胺 尼龙6 复合材料 异氰酸酯 

分 类 号：TQ323.6[化学工程—合成树脂塑料工业]