功能化的离子液体:手性离子液体的合成与应用  

Functional Ionic Liquids:Synthesis and Application of Chiral Ionic Liquids

作　　者：刘伟山[1] 陶国宏[1] 何玲[1] 寇元[1] 

机构地区：[1]北京大学化学与分子工程学院分子动态与稳态结构国家重点实验室绿色化学研究中心,北京100871

出　　处：《有机化学》2006年第8期1031-1038,共8页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金重点(No.20533010)资助项目.

摘　　要：手性在化学中占有重要地位.利用离子液体特殊的结构可调性质,将手性引入到离子液体结构中,可以获得具有手性的离子液体,从而可能广泛应用于手性合成、手性分离、手性催化等领域.汇总了至今报道的手性离子液体,从离子液体功能化设计的角度探讨其合成方法.针对手性离子液体可能的发展方向,再次强调了由天然手性源设计合成离子液体遵循的三个标准.Chirality shows an important role in chemistry. Ionic liquids have a special character different from common organic solvents for their alterable structures. Chiral ionic liquids can be gotten when chirality is induced to ionic liquids. They may be used to chiral synthesis, chiral separation, or chiral catalysis. Those chiral ionic liquids reported before are presented in this review, and discussed especially from the viewpoint of designing functionalized ionic liquids. Three criteria for designing and synthesizing ionic liquids from natural chiral materials are brought out.

关 键 词：离子液体 功能化 手性 合成 应用 

分 类 号：O621.25[理学—有机化学]