双(3-对甲苯基-2-硫代咪唑-1-基)-(3-甲基-5-苯基吡唑-1-基)硼氢酸根的镉及钴配合物的合成与结构表征(英文)  

Syntheses and Crystal Structures of Cadmium(II) and Cobalt(II) Complexes with Hydrobis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl) Borate

作　　者：舒谋海[1] 屠春来[1] 崔靖[1] 孙杰[2] 

机构地区：[1]上海交通大学化学化工学院,上海200240 [2]中国科学院上海有机化学研究所,上海200032

出　　处：《无机化学学报》2006年第8期1507-1510,共4页Chinese Journal of Inorganic Chemistry

基　　金：教育部留学回国人员科研启动基金资助项目

摘　　要：Two new complexes CdL2 (1) and CoL2 (2) were synthesized by reactions of L {L =hydrobis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)borate} with cadmium(II) and cobalt(II) acetate respectively, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S4H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC: 235514, 1; 244021, 2.Two new complexes CdL2 （1） and CoL2 （2） were synthesized by reactions of L {L =hydro[bis（3-p-tolyl-2- thioimidazol-1-yl）-（3-phenyl-5-methyl-pyrazol-1-yl）]borate} with cadmium（Ⅱ） and cobah（Ⅱ） acetate respectivelyl, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S4H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC： 235514, 1; 244021, 2.

关 键 词：三角架配体 镉 钴 晶体结构 

分 类 号：O614.242[理学—无机化学] O614.82[理学—化学]