UV_(-vis)/草酸铁络合物/H_2O_2法处理垃圾渗滤液的研究  

Study on Photodegradation of Landfill Leachate by UV/H_2O_2/ferrioxalate Complexes

作　　者：刘文辉[1,2] 刘增超[1] 赵晓光[3] 

机构地区：[1]西安工业学院材化学院 [2]西安科技大学西安710055 [3]西安科技大学

出　　处：《工业安全与环保》2006年第8期22-23,共2页Industrial Safety and Environmental Protection

摘　　要：在紫外光照下,利用H2O2和草酸铁络合物对垃圾渗滤液进行了处理,探讨了紫外光照时间、pH值、fenton试剂、草酸铵对垃圾渗滤液中CODCr去除率的影响。结果表明UV-vis/草酸铁络合物/H2O2法对垃圾渗滤液CODCr去除率有较好的效果,当操作条件是pH取3,反应时间为1h,H2O2投加量为1.4mL,H2O2/FeSO4.7H2O投加比(摩尔比)为5∶1,草酸铵投加量为5.5mL时,CODCr的去除率达到了78.8%。The photodegradation of landfill leachate by H2O2 - ferrioxalate complexes as a photo - oxidant under UV light source is studied. The effect of PH, fenton reagent, ammonium oxalate and reaction time on the removal rate of CODCr is discussed. The results show that removing CODCr in landfill leachate by fenton oxidation is very effective and rapid; the removal rate of CODCr is 78.8% when the operation condition is as follows： with pH 3, the reaction time 1 hour, the dosage of H2O2 1.4mL, the ratio of H202 and FeSO4·7H2O 5：1 and the dosage of ammonium oxalate 5.5 mL.

关 键 词：FENTON试剂 光助氧化 草酸铁络合物 垃圾渗滤液 

分 类 号：X703[环境科学与工程—环境工程]