4-酰基吡唑啉酮配合物的合成方法与结构  

Synthesis method and structure of complexes from 4-acylpyrazolone~

作　　者：李红新[1] 李锦州[1] 

机构地区：[1]哈尔滨师范大学化学系,黑龙江哈尔滨150080

出　　处：《化学工程师》2006年第7期25-27,共3页Chemical Engineer

基　　金：黑龙江省自然科学基金(B01-07);黑龙江省教育厅科研基金资助项目

摘　　要：综述了4-酰基吡唑啉酮及其配合物的合成方法和结构特征,介绍了非水溶剂法、水相合成法、固相合成法等合成方法适用的体系。分析评价了4-酰基吡唑啉酮以烯醇双氧、共轭双酮氧参与中心离子包含主族金属元素、副族金属元素、稀土金属元素等配位成键,形成6配位、8配位、单核、双核和多核配合物的结构关系。The synthesis method and structure charactertics of 4 - acylpyrazolone and its complexes were reviewed. The application system in the nonaqeous solvent method, the water phase synthetic method and the solid phase synthetic method were chiefly introduced. Yne structures of six- coordinated, eight- coordinated, mononuclear and dinudear and multinuclear complexes of acylpyrazolone were analysed and the bonding mode of acylpyrazolone through the enoldioxygen or conjugate diketone with central ions（main group, transition, rare metal ）were also discussed.

关 键 词：酰基吡唑啉酮 合成方法 结构 

分 类 号：O647.3[理学—物理化学]