降膜蒸发过程熵产分析  

Analysis of entropy generation in falling film evaporation

作　　者：陈曦[1] 汪建军[1] 朱家骅[1] 帅剑云[1] 冯昭华 

机构地区：[1]四川大学化学工程学院,四川成都610065 [2]福建省环境科学与工程研究设计院,福建福州350004

出　　处：《化工学报》2006年第7期1518-1524,共7页CIESC Journal

基　　金：国家高技术研究发展计划项目(2002AA647020);国家自然科学基金项目(20476063).~~

摘　　要：从热力学第二定律出发,将普适体系的熵产表达推广于降膜蒸发过程熵产分析并得到熵产计算式.引入单位熵产数并得到Reynolds数大于1450(cpμ/λ)-1.06(0.5-0.25ω)-1情况下和Reynolds数之间的定量关系,据此揭示了降膜蒸发过程熵产随降膜管内液膜厚度减小先降低再增大的规律,对应存在最小熵产数.与30×2×6000传热管内磷酸降膜蒸发实验数据对比结果吻合良好,表明本文熵产计算式可以根据过程的热力参数表达降膜蒸发过程的熵产规律,对过程强化和提高热力学效率具有实际指导意义.Based on the second law of thermodynamics for an open system under non-equilibrium state an intensive analysis of the entropy generation in the process of falling film evaporation was made. A quantitative correlation was deduced to calculate the unit entropy generation number, Ns from traditional Reynolds number and other parameters under the condition of Re〉1450 （cpμ/λ）^-0.16（0.5-0.25ω）^-1. It was unveiled that Ns decreased with decreasing thickness of the falling film and increased after the optimalω, which corresponded with a minimum value of Ns. The good agreement between the expressions of correlation and the results obtained from an experimental rig of falling film evaporation for phosphoric acid concentration in a vertical heated tube with the dimension ofФ30×2×6000 demonstrated that the correlation equation could be rationally used to predict the entropy generation in falling film evaporation. This theoretical prediction, calculated from ordinary thermal process parameters is useful in enhancement of thermodynamic efficiency in industrial processes.

关 键 词：降膜蒸发 熵产 单位熵产数 最小熵产分析 

分 类 号：TK123[动力工程及工程热物理—工程热物理]