PHOTOCATALYTIC HYDROGEN EVOLUTION FROM WATER SPLITTING UNDER VISIBLE LIGHT IRRADIATION ON NOVEL PHOTOCATALYST FULLENES-PVP-ZN0.999NI0.001S  

作　　者：XUE Zhixin YANG Guipeng CHEN Dianbao MA Xiaomei ZHANG Xiqin QUAN Zhenlan 

机构地区：[1]College of Chemical Engineering and Environment, Qingdao University, Qingdao 266071, China [2]Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266003, P.R. China [3]Fullerenes Materials Group, Qingdao University of Science and Technology, Qingdao 266071, China

出　　处：《Chinese Journal of Reactive Polymers》2006年第1期35-39,共5页中国反应性高分子（英文版）

基　　金：Key Project of Chinese Ministry of Education （No. 105105）, Program for New Century Excellent Talents in University of Chinese Ministry of Education （No. NCET-04-0643）, and the Taishan Mountain Scholar Construction Engineering Special Fund of Shandong Province, China.

摘　　要：Fullerenes （C60/C70） linked up to Ni-doped ZnS through the medium of an amphalic polymer polyvinyl pyrrolidone （PVP） to form a new kind of photocatalyst for hydrogen evolution from aqueous Na2S/Na2SO3 solution under visible light irradiation, the photocatalytic activities of this novel photocatalyst C60/C70-PVP- Zn0.999Ni0.001S are 3-5 fold higher compared with that of precurse catalyst Zn0.999Ni0.001S. This result could be attributed to Schottky barrier layer built between C60/C70 and Zn0.999Ni0.001S due to the electro-negativity of C60 and characteristic of being used as a multiple electron acceptor. C60 or C60/C70 its moiety, with its low energy first excited singlet state, is a good energy acceptor and in addition readily accepts multiple electrons, making it a potential electron accumulate as we know, which could protect the separation between electrons and holes against combination. This is an important reason for the marked increase of amount of H2 evolution during the photocatalytic process for the composite system C60/C70-PVP- Zn0.999Ni0.001S.

关 键 词：Fullerenes （C60/C70） PHOTOCATALYST Hydrogen Water splitting Visible light. 

分 类 号：TQ032.4[化学工程]