固体酸催化合成丁二酸二丁酯  

Synthesis of Dibutyl Succinate Catalyzed by Solid Acid

作　　者：刘美艳[1] 俞善信[1] 管仕斌[1] 

机构地区：[1]湖南师范大学化学化工学院,湖南长沙410081

出　　处：《化工中间体》2006年第8期27-29,共3页

基　　金：湖南省教育厅科研基金资助项目(01C022)

摘　　要：固体酸是有机合成中能够代替硫酸的良好催化剂。本文评述了对甲苯磺酸、氨基磺酸、强酸性阳离子交换树脂、六水三氯化铁、五水四氯化锡、十二水合硫酸铁铵、硫酸钛、一水硫酸氢钠和固体超强酸等催化剂催化合成丁二酸二丁酯的方法。建议对近年来开发的有应用前景的催化剂进行扩大试验与筛选。Solid acid was a good catalyst of organic synthesis and can be a substitute for sulphuric acid. The synthesis methods of dibutyl succinate catalyzed by p-toluene sulfonic acid, amino sulfonic acid,strongly acidic cationic exchange resin, ferric chloride hexahydrate, stannic chloride pentahydrate, copper sulfate , ammonium ferric sulfate dodecahydrate, titanium sulfate, sodium bisulfate monohydrate, and solid super acid et al were reviewed. It was suggested that the experiment and selection of promising catalyst developed in the recent years should be enhanced.

关 键 词：合成 丁二酸二丁酯 固体酸 催化 

分 类 号：O623.5[理学—有机化学] TQ225.242[理学—化学]