Addition of Allyltrimethylsilane to tert-Butanesulfinyl Imines Triggered by Tetra-n-butylammonium Fluoride  

作　　者：Wan Xuan ZHANG Xue Long HOU 

机构地区：[1]Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Faculty of Chemistry and Material Science, Hubei University, Wuhan 430062 [2]State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

出　　处：《Chinese Chemical Letters》2006年第8期1037-1040,共4页中国化学快报（英文版）

摘　　要：The addition of allyltrimethylsilane to tert-butanesulfinyl imines triggered by tetra-n-butylammonium fluoride （TBAF） in the presence of 4A molecular sieves has been studied, and homoallylsulfinamides were obtained in good yields with moderate to high diastereoselectivities.The addition of allyltrimethylsilane to tert-butanesulfinyl imines triggered by tetra-n-butylammonium fluoride （TBAF） in the presence of 4A molecular sieves has been studied, and homoallylsulfinamides were obtained in good yields with moderate to high diastereoselectivities.

关 键 词：Stereoselective addition tert-butanesulfinyl imines ALLYLTRIMETHYLSILANE tetra-n-butylammonium fluoride. 

分 类 号：O623.73[理学—有机化学] O623.8[理学—化学]