固有手性杯芳烃的研究  

Progress in Inherently Chiral Calixarenes

作　　者：罗钧[1] 郑企雨[1] 陈传峰[1] 黄志镗[1] 

机构地区：[1]中国科学院化学研究所,北京100080

出　　处：《化学进展》2006年第7期897-906,共10页Progress in Chemistry

基　　金：国家自然科学基金项目资助(No.20372064)

摘　　要：固有手性杯芳烃是指在杯芳烃三维骨架上引入数个非手性基团使之不再具有对称面或反转中心而呈现出整体手性。本文综述了固有手性杯芳烃的合成、光学拆分及其在手性识别和不对称催化领域的应用。Inherently chiral calixarenes denote calixarenes whose chirality is based on the absence of a planar symmetry or an inversion center in the molecules as a whole through the desymmetric array of several achiral groups upon the three-dimensional calix-skeletons. Herein the synthesis and optical resolution of inherently chiral calixarenes and their applications in enantioselective recognition and asymmetric catalysis are reviewed.

关 键 词：杯芳烃 固有手性 合成 光学拆分 手性识别 不对称催化 

分 类 号：O625.1[理学—有机化学]