硒芳香杂环-铜配合物的固相合成与表征  

Two ways synthesis of coppera(Ⅱ)complexes with heterocyclic aromatic selenium compounds

作　　者：睢超霞[1] 杨芳[1] 郑文杰[1] 白燕[1] 

机构地区：[1]暨南大学化学系

出　　处：《化学研究与应用》2006年第8期947-951,共5页Chemical Research and Application

基　　金：国家自然科学基金(20271022)资助项目;广东省自然科学基金(010369)资助项目

摘　　要：A series of complexes were synthesized using piazselenole（NS） 5-methyl piazselenole（MB） and 4,5-benzopiazselenole（BS）as ligands and Cu2+ as cation in liquid-phase and solid-phase reaction.The complexes were characterized and compared by ICP-AES,EA,IR,UV-Vis,and XRD etc.The coordinating mechanism and the spectral properties are also discussed.A series of complexes were synthesized using piazselenole（NS） 5 -methyl piazselenole（MB） and 4,5 -benzopiazselenole（BS） as ligands and Cu^2＋ as cation in liquid- phase and solid- phase reaction. The complexes were characterized and compared by ICP- AES,EA,IR,UV-Vis,and XRD etc. The coordinating mechanism and the spectral properties are also discussed.

关 键 词：硒芳香杂环 铜配合物 合成与表征 固相反应 

分 类 号：O627.12[理学—有机化学]