A3钢镀锌层钼酸盐钝化膜的组成和性能  

The performance of the molybdate passivation film on galvanization layer of A3 steel

作　　者：郝建军[1] 安成强[1] 邵忠财[2] 常丽丽[1] 刘常升[1] 

机构地区：[1]东北大学材料与冶金学院,沈阳110004 [2]沈阳理工大学环境与化学工程学院,沈阳110168

出　　处：《材料研究学报》2006年第4期427-430,共4页Chinese Journal of Materials Research

基　　金：国家重点基础研究发展计划"973"资助项目(G19990650).~~

摘　　要：使用加速腐蚀试验和X射线光电子能谱(XPS)等手段,研究了A3钢镀锌层钼酸盐钝化膜的组成和性能．结果表明,钼酸盐钝化膜膜层厚度大于35 nm,钝化膜外层钼元素以Mo3+、Mo6+形式存在,主要组成为:MoO3,Mo(OH)3,Zn(OH)2, ZnO,ZnMoO4;钝化膜内层钼元素以Mo3+形式存在,主要由Mo2O3,Mo(OH)3,ZnO,ZnMo2O4组成．钝化膜表面层中的MoO42-具有抗氯离子等侵蚀性阴离子的破坏作用,使钝化膜具有阳离子选择性,提高镀锌钝化膜的耐蚀性能．The molybdate passivation film formed on galvanization layer of A3 steel was investigated. The results showed that the corrosion resistance increased by using molybdaye as the passivation agent, and the characteristic of passivition was close to use chromate as the passivation agent. The thickness of the passivation film was nearly to 35 nm and the passivition film was divided into two layers. The outerlayer was formed by Mo^3＋ and Mo^6＋, and the main of the outer layer were MoO3, Mo（OH）3, Zn（OH）2, ZnO and ZnMoO4. The in-layer was formed by Mo^3＋, and the main composition of the in-layer were Mo2O3, Mo（OH）3, ZnO, and ZnMo2O4. Because of existing of the anion MoO4^2- in the outer-layer, the passivition film has the characteristic of cation selection and it increases the corrosion resistance of the passivition film on the galvanization layer.

关 键 词：材料失效与保护 钝化 XPS分析 钼酸盐 

分 类 号：O484[理学—固体物理]