有机硅高沸物催化裂解制单硅烷催化剂研究进展  

Research on advances of converting organosilicon high-boiling components to methylchlorosilane by catalytic decomposition

作　　者：熊艳锋[1] 张宁[1] 

机构地区：[1]南昌大学理学院化学系,江西南昌330047

出　　处：《化工进展》2006年第8期864-866,共3页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金资助项目(No.20562007);江西省教育厅2003年科技项目

摘　　要：介绍了近年来通过高温裂解法、催化裂解法将有机硅高沸物转化成单硅烷的研究进展,重点评述了催化裂解高沸物的氯化铝及其复合含盐催化剂、有机胺及其盐催化剂、过渡金属及其化合物催化剂、分子筛和活性炭催化剂。Advances in utilizing the organosilicon high-boiling components formed during the preparation of methylchlorosilane via direct synthesis to produce valuable methylchlorosilanes are reviewed. The catalytic conversion of the organosilicon high-boiling components to methyldichlorosilanes by splitting decomposition is particularly presented. The utilization of organosilicon high-boiling components in China is briefly described. The development of utilizing organosilicon high-boiling components is discussed.

关 键 词：有机硅高沸物 催化裂解 甲基氯硅烷 二甲基二氯硅烷 

分 类 号：TQ264.11[化学工程—有机化工] TQ426.94