超临界二氧化碳中的不对称合成研究进展  

Research Progress of Asymmetric Synthesis in Supercritical Carbon Dioxide

作　　者：李志伟[1] 曹丽琴[1] 胡仁权[1] 焦吉庆[1] 陈六平[1] 

机构地区：[1]中山大学化学与化学工程学院,广东广州510275

出　　处：《广州化工》2006年第4期5-12,共8页GuangZhou Chemical Industry

摘　　要：主要介绍了超临界二氧化碳中的不对称合成反应,如不对称氢甲酰化反应、碳-碳双键的不对称催化氢化、亚胺不对称催化还原、烷基化反应、不对称D-A反应、醇醛缩合反应、不对称酶催化反应等的研究现状,同时对离子液体与超临界二氧化碳构成的混合介质中的不对称合成研究进展作了介绍,对这一领域中若干基本问题的研究发展趋势进行了分析讨论。The research progress on several asymmetric synthesis in supercritical carbon dioxide was presented in this paper, which included hydroformylation, hydrogenation of C- C double bonds and imines, dialsalder reactions, alkylation, mukaiyama reactions and enzymic catalytic reactions. The asyrmmetric synthesis in mixed medium consisting of the ionic liquid and supercritical carbon dioxide were aiso introduced. The basic problems both in theory and in experiments in this field to be studied were proposed.

关 键 词：超临界二氧化碳 离子液体 不对称催化 对映选择性 

分 类 号：O621.34[理学—有机化学] TS193.59[理学—化学]