RAFT Miniemulsion Polymerization of MMA with Cumyl Dithiobenzoate as Chain Transfer Agent  

作　　者：Tian Ying GUO Dong Lin TANG Jing Wei ZHU Mou Dao SONG Bang Hua ZHANG 

机构地区：[1]Key Laboratory of Functional Polymer Materials, Ministry of Education, Institute of Polymer Chemistry, Nankai University, Tianjin 300071

出　　处：《Chinese Chemical Letters》2006年第9期1247-1250,共4页中国化学快报（英文版）

摘　　要：Reversible addition-fragmentation transfer （RAPT） miniemulsion polymerizations for PMMA with cumyl dithiobenzoate （CDB） as a chain transfer agent （CTA） has been carried out. Higher temperature made the polymerization much faster and the PDI remained below 1.20, when the temperature was upon 70 ℃.Reversible addition-fragmentation transfer （RAPT） miniemulsion polymerizations for PMMA with cumyl dithiobenzoate （CDB） as a chain transfer agent （CTA） has been carried out. Higher temperature made the polymerization much faster and the PDI remained below 1.20, when the temperature was upon 70 ℃.

关 键 词：RAFT polymerization MINIEMULSION chain transfer agent cumyl dithiobenzoate. 

分 类 号：O631.5[理学—高分子化学]