BOPP膜表面化学键组装制备多层膜  

Fabrication of a multilayer construction on a bi-oriented polypropylene (BOPP) film surface via chemical bonding assembly

作　　者：赵洪池[1] 刘莲英[1] 杨万泰[1] 

机构地区：[1]北京化工大学材料科学与工程学院

出　　处：《北京化工大学学报（自然科学版）》2006年第4期30-33,共4页Journal of Beijing University of Chemical Technology(Natural Science Edition)

基　　金：国家杰出青年科学基金(20025415);国家自然科学基金重点项目(50433040);北京市教委共建项目高分子化学与物理学科建设重点项目(XK100100433/XK100100540)

摘　　要：通过紫外光照射将半频哪醇自由基偶合到双向拉伸聚丙烯(BOPP)膜表面,利用该偶合基团上的羟基与对苯二甲酰氯(TPC)和双酚A(BPA)进行交替反复的逐步缩合反应,制备了以共价键结合的多层组装膜。采用紫外(UV)、红外光谱(ATR-FTIR)跟踪和证实了组装膜的形成,并且膜的组装比较规则。A multilayer construction has been fabricated on a bi-oriented polypropylene （BOPP） surface via a chemical bonding assembly process. The first step in the fabrication process involves the introduction of semipinacol groups onto the BOPP surface by hydrogen abstraction by benzophenone （BP） and coupling of the resultant semipinacol radicals with the surface under UV irradiation. The second step involves a condensation reaction between the hydroxyl group of the semipinacol moiety and terephthaloyl chloride （TPC） followed by successive condensation reactions of bis-phenol A （BPA） and TPC. The formation of the assembled film can be conveniently monitored by UV spectroscopy and ATR-FTIR spectroscopy.

关 键 词：多层膜 化学键组装 双向拉伸聚丙烯(BOPP)膜 

分 类 号：O632.12[理学—高分子化学]