杂多酸催化合成聚氧丙烯甘油醚  

Preparation of Polyoxypropylene Glycerin Ether Catalyzed by HPA and Its Salt

作　　者：岳淑美[1] 唐艳茹[1] 丁鹏[1] 高丽娟[1] 

机构地区：[1]长春师范学院化学学院,吉林长春130032

出　　处：《长春师范学院学报（自然科学版）》2006年第4期41-45,共5页Journal of Changchun Teachers College

摘　　要：采用可溶性固体杂多酸作均相反应催化剂,以及不可溶性固体杂多酸盐作非均相反应催化剂,合成了聚氧丙烯甘油醚。实验结果表明,采用杂多酸作催化剂在中温、常压条件下,就可合成了产率较高的符合工业技术指标的聚氧丙烯甘油醚。用元素分析、IR、1HNMR和羟值的测定确定了产物的组成和分子量,得出最佳合成条件。Polyether polyols （PE） are the primary material in the synthesis of polyurethane plastic foams, elastomers and so on. In this paper,We discussed the application of the heteropoly acid compounds （or salts） as the catalyst in the synthesis of PE under middle temperature and normal pressure. PE were characterized by elementary analysis, and IR. molecular weight was obtained through their hydroxide numerical value.

关 键 词：聚氧丙烯甘油醚 开环聚合 磷钨酸 催化剂 

分 类 号：O63[理学—高分子化学]