meso-四(对烷氧基苯基)卟啉合银的合成、表征和性能研究  

Synthesis,Characterization and Properties of Silver Complexes of meso-tetra(p-Alkoxylphenyl)porphyrin

作　　者：林凯[1] 赵鸿斌[1] 刘捷频[1] 陈科[1] 许兰兰[1] 

机构地区：[1]湘潭大学化学学院,湖南湘潭411105

出　　处：《化学研究》2006年第3期5-9,共5页Chemical Research

基　　金：湖南省自然科学基金资助项目(04JJ40013;01JJY2046)

摘　　要：合成了10种未见文献报道的m eso-四(对烷氧基苯基)卟啉合银配合物,研究了其合成、分离、纯化方法.用红外光谱、紫外-可见光谱、核磁共振氢谱、质谱和元素分析等对各个化合物的结构进行了表征.研究了其荧光性能,用差示扫描量热仪和偏光显微镜对其液晶性质进行了研究,发现10个配合物均具有液晶性.10 silver complexes of meso-tetra（p-alkoxyl） phenyl porphyrin[ meso-T（p-ROP） PAg] were synthesized. All the complexes were characterized by IR , UV-Vis, ^1H NMR, MS and elemental analysis. Fluorescence properties of the complexes were studied. The liquid crystal properties of the complexes were investigated by differential scanning calorimetry and polarizing microscope. All complexes were found to exhibit liquid crystal properties.

关 键 词：卟啉 银 配合物 液晶性 

分 类 号：O641.4[理学—物理化学]