用英安岩和粉煤灰合成ZSM—5分子筛研究  

Studies on the Synthesis of ZSM 5 Molecular Sieve Using Dacite and Fine Coal Ash

作　　者：焦庆祝[1,2] 庞文琴[1,2] 霍启升 

机构地区：[1]烟台师范学院化学系 [2]吉林大学化学系

出　　处：《硅酸盐通报》1996年第4期29-31,38,共4页Bulletin of the Chinese Ceramic Society

摘　　要：分别以英安岩和粉煤灰为原料，采用自生压力下水热合成方法，以四丙基溴化铵为模板剂，通过Ｆ离子存在的微酸性介质和碱性介质两个途径，均合成了ＺＳＭ—５分子筛。样品晶胞参数为：ａ＝２．０１１ｎｍ，ｂ＝１．９９８ｎｍ，ｃ＝１．３３７ｎｍ。该分子筛孔道畅通，热稳定性高。ZSM 5 molecular sieve was synthesized from dacite and fine coal ash respectively in hydrothermal system at autogeneous pressure.The synthesis runs were carried out in basic medium and in weak acid medium respectively in the presence of F anion. The unit cell parameters of the sample are:a=2.011nm,b=1.998nm,c=1.337nm.The molecutar sieve has got opened pores and high thermal stability and can be used as catalyst at high temperature.

关 键 词：英安岩 粉煤灰 合成 分子筛 

分 类 号：TQ424.25[化学工程]